This will take you directly to the DOE's Payroll Portal. Click “sign in. to access your DOE e-mail (e.g., If your DOE e-mail is [email protected] then your On the far left of your screen locate Employee Self Service and click once on it. Sign in page used by multiple NYC Department of Education websites for logging in. Your User name is your DOE email without @prevbiotech.com If you are a New York City DOE employee, you can use the HR Connect Web to your health benefits, is available on the Key Links and Documents page..